Zonal Winds Between 25 and 120 Km Retrieved from Solar Occultation Spectra

Atmospheric winds at heights between 25 and 120 km have been retrieved with precisions of 5/ms from the Doppler shifts of atmospheric absorption lines measured from a satellite-borne instrument. Lines of the upsilon 3 CO2 and upsilon 2 H2O rotation-vibration bands caused by gases in the instrument allowed the instrumental frequency scale to be absolutely calibrated so that accurate relative speeds could be obtained. By comparing the positions of both sets of instrumental lines the calibration of the frequency scale was determined to be stable to a precision of less than 2 x 10(-5) cm during the course of each occultation. It was found that the instrumental resolution of 0.015 cm after apodization, the signal to noise ratio of about 100 and stable calibration allowed relative speeds to be determined to a precision of 5 ms or better by using small numbers of absorption lines between 1600 and 3200 cm. Absolute absorption line positions were simultaneously recovered to precisions of 5 x 10(-5) cm or better. The wind speed profiles determined from four sunset occultations and one sunrise occultation show remarkable similarities in the magnitudes and directions of the zonal wind velocities as functions of height. These wind profiles appear to be manifestations of atmospheric tides

Solar Radiation

Author Institution: Department of Physics and Astronomy, The Ohio State University, Columbus 1

Synthesis and Applications of Rhodacyclopentanones Derived From C-C Bond Activation

Rhodacyclopentanones, an “sp(3)-rich” class of metallacycle, underpin an emerging range of catalytic methodologies for the direct generation of complex scaffolds. This review highlights strategies for accessing rhodacyclopentanones (and related species) by C-C bond activation of cyclobutanones or cyclopropanes. The scope and mechanism of methodologies that exploit these activation modes is outlined

Directed carbonylative (3+1+2) cycloadditions of amino-substituted cyclopropanes and alkynes: reaction development and increased efficiencies using a cationic rhodium system

AbstractUrea-directed carbonylative insertion of Rh(I)-catalysts into one of the two proximal C–C bonds of aminocyclopropanes generates rhodacyclopentanone intermediates. These are trapped by N-tethered alkynes to provide a (3+1+2) cycloaddition protocol that accesses N-heterobicyclic enones. Stoichiometric studies on a series of model rhodacyclopentanone complexes outline key structural features and provide a rationale for the efficacy of urea directing groups. A comprehensive evaluation of cycloaddition scope and a ‘second generation’ cationic Rh(I)-system, which provides enhanced yields and reaction rates for challenging substrates, are presented

Identification of a novel retroviral gene unique to human immunodeficiency virus type 2 and simian immunodeficiency virus SIVMAC

Human and simian immunodeficiency-associated retroviruses are extraordinarily complex, containing at least five genes, tat, art, sor, R, and 3' orf, in addition to the structural genes gag, pol, and env. Recently, nucleotide sequence analysis of human immunodeficiency virus type 2 (HIV-2) and simian immunodeficiency virus SIVMAC revealed the existence of still another open reading frame, termed X, which is highly conserved between these two viruses but absent from HIV-1. In this report, we demonstrate for the first time that the X open reading frame represents a functional retroviral gene in both HIV-2 and SIVMAC and that it encodes a virion-associated protein of 14 and 12 kilodaltons, respectively. We also describe the production of recombinant TrpE/X fusion proteins in Escherichia coli and show that sera from some HIV-2-infected individuals specifically recognize these proteins

Detailed 3D Fault Representations for the 2019 Ridgecrest, California, Earthquake Sequence

We present new 3D source fault representations for the 2019 M 6.4 and M 7.1 Ridgecrest earthquake sequence. These representations are based on relocated hypocenter catalogs expanded by template matching and focal mechanisms for M 4 and larger events. Following the approach of Riesner et al. (2017), we generate reproducible 3D fault geometries by integrating hypocenter, nodal plane, and surface rupture trace constraints. We used the southwest–northeast‐striking nodal plane of the 4 July 2019 M 6.4 event to constrain the initial representation of the southern Little Lake fault (SLLF), both in terms of location and orientation. The eastern Little Lake fault (ELLF) was constrained by the 5 July 2019 M 7.1 hypocenter and nodal planes of M 4 and larger aftershocks aligned with the main trend of the fault. The approach follows a defined workflow that assigns weights to a variety of geometric constraints. These main constraints have a high weight relative to that of individual hypocenters, ensuring that small aftershocks are applied as weaker constraints. The resulting fault planes can be considered averages of the hypocentral locations respecting nodal plane orientations. For the final representation we added detailed, field‐mapped rupture traces as strong constraints. The resulting fault representations are generally smooth but nonplanar and dip steeply. The SLLF and ELLF intersect at nearly right angles and cross on another. The ELLF representation is truncated at the Airport Lake fault to the north and the Garlock fault to the south, consistent with the aftershock pattern. The terminations of the SLLF representation are controlled by aftershock distribution. These new 3D fault representations are available as triangulated surface representations, and are being added to a Community Fault Model (CFM; Plesch et al., 2007, 2019; Nicholson et al., 2019) for wider use and to derived products such as a CFM trace map and viewer (Su et al., 2019)

Detailed 3D Fault Representations for the 2019 Ridgecrest, California, Earthquake Sequence

We present new 3D source fault representations for the 2019 M 6.4 and M 7.1 Ridgecrest earthquake sequence. These representations are based on relocated hypocenter catalogs expanded by template matching and focal mechanisms for M 4 and larger events. Following the approach of Riesner et al. (2017), we generate reproducible 3D fault geometries by integrating hypocenter, nodal plane, and surface rupture trace constraints. We used the southwest–northeast‐striking nodal plane of the 4 July 2019 M 6.4 event to constrain the initial representation of the southern Little Lake fault (SLLF), both in terms of location and orientation. The eastern Little Lake fault (ELLF) was constrained by the 5 July 2019 M 7.1 hypocenter and nodal planes of M 4 and larger aftershocks aligned with the main trend of the fault. The approach follows a defined workflow that assigns weights to a variety of geometric constraints. These main constraints have a high weight relative to that of individual hypocenters, ensuring that small aftershocks are applied as weaker constraints. The resulting fault planes can be considered averages of the hypocentral locations respecting nodal plane orientations. For the final representation we added detailed, field‐mapped rupture traces as strong constraints. The resulting fault representations are generally smooth but nonplanar and dip steeply. The SLLF and ELLF intersect at nearly right angles and cross on another. The ELLF representation is truncated at the Airport Lake fault to the north and the Garlock fault to the south, consistent with the aftershock pattern. The terminations of the SLLF representation are controlled by aftershock distribution. These new 3D fault representations are available as triangulated surface representations, and are being added to a Community Fault Model (CFM; Plesch et al., 2007, 2019; Nicholson et al., 2019) for wider use and to derived products such as a CFM trace map and viewer (Su et al., 2019)